PMPlayer ( Picomixer Media Player )
you can have a direct video call ( without an intermediate server ).
You can use any standard network for this job ( including Internet, Intranet, LAN and so on ),
But given that this is a direct video call, so you and your partner should have valid IP address !
Also your device should have the required hardware including a webcam and a microphone.
Note: According to your network bandwidth you can adjust the video size, quality and frame rate.
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Direct Video Call